If a battery ruptures, may be … New Reagents for Selective Metalation, Deprotonation, and 1,2-Additions. Symptoms may be delayed. Pain. (lithium, thionyl chloride) are considered hazardous under US OSHA and are subject to the requirements of 29 CFR 1200 Hazard Communication.. Lithium Battery Safety With proper use and handling, lithium batteries have demonstrated an excellent safety record. May … eCl@ss 38050203 . SUPPLEMENTARY SAFETY AND HEALTH DATA: If the battery is broken or leaked the main hazard is the electrolyte. F3��-�5�"���:܂���.u�N�m�
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l�;� �ü�,���8�8�:��H�} Many reactions may cause fire or explosion. Info. Material Safety Data Sheet or SDS for Lithium chloride 105679 from Merck for download or viewing in the browser. Also, in biochemical applications, it can be used to precipitate RNA from cellular extracts.[8]. Material Safety Data Sheet Lithium chloride MSDS Section 1: Chemical Product and Company Identification Product Name: Lithium chloride Catalog Codes: SLL1366 CAS#: 7447-41-8 RTECS: OJ5950000 TSCA: TSCA 8(b) inventory: Lithium chloride CI#: Not available. Molecular Weight 42.39 . Large doses of lithium may cause dizziness, prostration, and kidney damage. Section 1: Chemical Product and Company Identification. Pain. 3 Effective date : 10.24.2014 Page 2 of 7 Lithium Chloride, Reagent Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com Lithium Chloride is an antiviral metal halide utilized in a variety of assays to study cell-fate and neurobiology. �('��X˘��P���� �C�T�� ��8w+���xq|.�2��"��#c�(HZ���G�S�|��N*�;� LEAKING FLUID IS CORROSIVE. 7447-41-8 Lithium chloride min 99% 231-212-3 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW Harmful in contact with skin and if swallowed. [6] Mono-, tri-, and pentahydrates are known. Fires may be fought but only from safe fire fighting distance, evacuate all persons from immediate area of fire. [11], Lithium chloride has been shown to have strong acaricidal properties, being effective against Varroa destructor in populations of honey bees. [5] Anhydrous LiCl is prepared from the hydrate by heating with a stream of hydrogen chloride. h�bbd```b``��5 ��4�d���E4�lq�x-�d���K"�w�$7����3��$S�U��)�,`��1`��`���Ge �"�
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The salt is a typical ionic compound (with certain covalent characters) , although the small size of the Li ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties. For a short time in the 1940s lithium chloride was manufactured as a salt substitute, but this was prohibited after the toxic effects of the compound (tremors, fatigue, nausea) were recognized. It is used as a desiccant for drying air streams. Lithium chloride is mainly used for the production of lithium metal by electrolysis of a LiCl/KCl melt at 450 °C (842 °F). The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). Health Hazard SYMPTOMS: Symptoms of exposure to this compound may include vomiting, profuse diarrhea, ataxia, coma, convulsions and local irritation of the skin, eyes and mucous membranes. One instance of reversible noticeable hepatotoxicity has been reported. 5.4 Further information No data available. NACRES NA.23 1960]. Lithium chloride has been extensively tested for REACH registration Acute Effects From Overexposure: No data available for the formulation. Jr,XH�Q��ƻ/�W�JJ���]�p��="�'�����!�jl��x��tI�G����.�E����EN�>�+J�;P�YF�T��|$��{()F%����{E���[ Y �f{BC�@تݯ5��jG�i��="�! Cold water can be used. MDL number MFCD00011078. Lithium Battery Safety With proper use and handling, lithium batteries have demonstrated an excellent safety record. Effects of exposure to Lithium: Fire: Flammable. EC Number 231-212-3. Additionally, lithium chloride can itself be used as a hygrometer. It is not toxic by ingestion, but by its corrosive nature can be irritating to the skin and eyes, it can also irritate the nostrils (National Institute for Occupational Safety and Health, 2015). PubChem Substance ID 24852187. 402 0 obj
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Flush eyes with running water for at least 15 minutes, keeping eyelids open. Haz. Laboured breathing. Product Identification Synonyms: Lithium monochloride CAS No. [5] In more specialized applications, lithium chloride finds some use in organic synthesis, e.g., as an additive in the Stille reaction. ��u�u��f5kx��ތ�L.���b8>φ����t6?�Lnso& ��w��" Causes redness and pain. ��c��}��M�(�Ohv�-ʿ (�s�
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*�X��`=� Lithium chloride is used as a relative humidity standard in the calibration of hygrometers. The electrolyte is mainly solution of Lithium chloride (LiCl), and aluminum chloride (AlCl 3) in Thionyl chloride (SOCl 2). Fires may be fought but only from safe fire fighting distance, evacuate all persons from immediate area of fire. LiCl also absorbs up to four equivalents of ammonia/mol. The salt is a typical ionic compound (with certain covalent characters) , although the small size of the Li+ ion gives rise to properties not seen for other alkali metal chlorides, such as extraordinary solubility in polar solvents (83.05 g/100 mL of water at 20 °C) and its hygroscopic properties.[5]. It is used as a dessicant. Lithium Chloride No exposure limit established No exposure limit established Appropriate Engineering Controls : Whenever possible the use of local exhaust ventilation or other engineering controls is the preferred method of controlling exposure to airborne dust … Ey… Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. 6bd�H�@1�:� Cc7�����s�L�s�4���{�iWzm�} )���� �y�. 1962, Chem. Product Name: Lithium chloride. NFPA SUPPLIER Santa Cruz Biotechnology, … HUMAN EXPOSURE AND TOXICITY: Acute poisoning in man reported after 4 doses of 2 g each of lithium chloride, causing weakness, prostration, vertigo, and tinnitus. Lithium chloride powder, ≥99.98% trace metals basis CAS Number 7447-41-8. Treatment with Pamelor could be resumed 24 hours after the last dose of linezolid or intravenous methylene blue (see WARNINGS). LiCl is also used as a brazing flux for aluminium in automobile parts. The equilibrium LiCl concentration in the resulting solution is directly related to the relative humidity of the air. While the citrate, carbonate, and orotate salts are currently used to treat bipolar disorder, other lithium salts including the chloride were used in the past. Lithium chloride is a chemical compound with the formula LiCl. Chlorine vapors and lithium react producing a luminous flame [Mellor 2, Supp. Material Safety Data Sheet Lithium chloride MSDS Section 1: Chemical Product and Company Identification Product Name: Lithium chloride Catalog Codes: SLL1366 CAS#: 7447-41-8 RTECS: OJ5950000 TSCA: TSCA 8(b) inventory: Lithium chloride CI#: Not available. In developing Xenopus embryos, lithium chloride is observed to exert inhibition of GSK-3β (glycogen synthase kinase-3β), yet not reported to be a general inhibitor of other protein kinases. >V��DUg_?�ٴ�ӯu����Uq�Y ���-�:���X���%�u8�{Y}�����������s��ގ�vfY��o ���MB͊���Z�
�uH�Ь�J?�/���mP8��1���4gR:͙�L��(Mj���P�s�lO��h5�枠8:=>���N��&%��+��|������Zxku|��M>FH,c`�X�`��. No envisaged effects other than acute effects from local irritation 1:380. 5.2 Special hazards arising from the substance or mixture Hydrogen chloride gas, Lithium oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. [12], Lithium salts affect the central nervous system in a variety of ways. words matched: chloride, Lithium SRA028 – Rainbow flames Alcohol is added to a series of beakers or crystallizing dishes containing metal salts and boric acid. Severe deep burns. (j) aspiration hazard Lithium chloride, a solid, does not present an aspiration hazard. COPPER CHLORIDE page 2 of 6 This Fact Sheet is a summary source of information of all potential and most severe health hazards that may result from exposure. Skin: Redness. Chronic toxicity symptoms following ingestion of nonlethal doses of lithium chloride with … The salt forms crystalline hydrates, unlike the other alkali metal chlorides. Lithium chloride is a stable compound incompatible with strong oxidizing agents, strong acids, bromine trichloride, bromine trifluoride. H�̗Mk�@�����jG�o9d������B���/�@Ӕ���^���M֘���k�<3�����,N��������ԕ���F�ÇWu%����G1z�����Hp]W�����`�1uW.t�1M�i�[�� c��14��1]��ki;K�A~��Ur��L��vZ�s�=�P>�m
:�YWA���at. Boron trifluoride reacts with incandescence when heated with lithium [Merck 11th ed. Abdominal pain. May cause headache, muscle weakness and incoordination, and confusion. ��Ʉ��[H8���s\�����`���E$Y�}u1��_ Lithium chloride SDS Safety Data Sheet for Lithium chloride 105679. As with any other ionic chloride, solutions of lithium chloride can serve as a source of chloride ion, e.g., forming a precipitate upon treatment with silver nitrate: Lithium chloride is produced by treatment of lithium carbonate with hydrochloric acid. eψa������5���s_��؟nڂK��YG�@�1���(c���)�%�r�7�ޤ����'��lJC��X
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�?Mo4%BH�ף](O7�"B��»c�B�`L1�6� Section 3: Hazards Identification. Lithium Coupon. The percent relative humidity at 25 °C (77 °F) can be estimated, with minimal error in the range 10–30 °C (50–86 °F), from the following first order equation: RH=107.93-2.11C, where C is solution LiCl concentration, percent by mass. LITHIUM CHLORIDE . Irritating to eyes and skin. Shortness of breath. MSDS-0002 Rev. Lithium chloride is also used as a flame colorant to produce dark red flames. This deliquescent salt forms a self-solution when exposed to air. ACUTE/CHRONIC HAZARDS: This compound is a mild irritant. Dehydration, weight loss, slurred speech, blurred vision, sensory loss, ataxia (failure of muscular coordination), tremors, and convulsions may occur. (lithium, sulfuryl chloride, thionyl chloride, chlorine) are considered hazardous under US OSHA and are subject to the requirements of 29 CFR 1200 Hazard Communication. SUPPLEMENTARY SAFETY AND HEALTH DATA: If the battery is broken or leaked the main hazard is the electrolyte. Lithium chloride is a chemical compound with the formula LiCl. Maleic anhydride decomposes explosively in the presence of lithium [Chemical Safety Data Sheet SD-88. [7] The anhydrous salt can be regenerated by heating the hydrates. 5.4 Further information No data available SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Linear Formula LiCl . ;(Q�c+�Z�JY��V���'"�7�XJ˵��p���d~��Mt�R~���ˈY�Z>���&o�ә�9j8|��k8|��إ�s.�lw��;��h}4ҳ�Y���L`��1��ʧ��gm�_6��g����٢C�l=���8yv� ���d��%��S?�+�#�,�3�2���=JLi��w! Inhalation: Burning sensation. }�,@����)�����H �` E0�
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Gives off irritating or toxic fumes (or gases) in a fire. Ingestion: Abdominal cramps. h��X�n7�}Iи���|�IZ�n]���om�dHJ�}�pW�ʖ��b䡅�"��f�̜��$��� m�De^y�Qx�5R()�a�P�T�P6B��H:T�P��`�ˡB/�,2Ahmx�(���R�@U�H^�ja��a��+Y�� %PDF-1.6
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safety hazards of Copper Chloride to potentially exposed workers. Re: Lithium Chloride safety and alternatives CausticSymmetry on Sat Nov 14, 2015 11:23 am Pumbaa - My own success was based on internal use only, so my experience is … Lithium chloride lbs lbs lbs SARA Hazard Categories: Acute Chronic Flammability Pressure Reactivity Lithium chloride Clean Air Act Categories: SOCMI HAP Volatile HAP Organic HAP Ozone Depleting Lithium chloride The information presented above is offered for informational purposes only. : 7447-41-8 Molecular Weight: 42.39 Chemical Formula: LiCl Product Codes: J.T. Eyes: Redness. At 25 °C (77 °F) a saturated solution (45.8%) of the salt will yield an equilibrium relative humidity of 11.30%. Cough. 1989]. Duration of exposure, concentration of the substance [��
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